|
|||||
|
|
The structure and absolute configuration of verticillol,a macrocyclic diterpene alcohol from the wood of sciadopitys verticillata sieb. et zucc. (taxodiaceae) |
|
| Authors: | Bengt Karlsson Anne-Marie Pilotti Anne-Charlotte Söderholm Torbjörn Norin Stefen Sundin Masashi Sumimoto |
| Institution: | Department of Structural Chemistry, Arrhenius Laboratory, University of Stockholm, S-106 91 Stockholm, Sweden;Department of Organic Chemistry, Royal Institute of Technology, S-100 44 Stockholm, Sweden;Swedish Forest Products Research Laboratory, P.O. Box 5604, S-114 86 Stockholm, Sweden;Faculty of Agriculture, Kyushu University, Fukuoka, Japan |
| Abstract: | The structure of verticillol diepoxide 4 has been established by direct single crystal X-ray analysis. The structure of verticillol 5 follows from the chemical correlation to the diepoxide 4 as well as from NMR-LIS studies on verticillol which also provide evidence for the conformation of this alcohol. The absolute configuration of verticillol 5 has been assigned on the basis of CD data for the verticillol norketodiepoxide 6a. |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ | |