Hochdruckversuche—X: Enantioselektive wagner-meerwein umlagerung in chiralen lösungsmitteln bei hohem druck |
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| Authors: | H.P. Kraemer H. Plieninger |
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| Affiliation: | Organisch-Chemisches Institut der Universiät Heidelberg, DeutschlandGermany |
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| Abstract: | In the Wagner-Meerwein rearrangement of 1,1-Diphenyl-2-methyl-2-(4-methoxyphenyl)oxiran 1 an enantioselektive synthesis takes place in chiral solvents only at high pressure. The asymmetric induction reaches up to 14-proz. depend on the chiral solvent. A pressuie dependency of the product distribution also is reported. |
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