A transannular reaction during the base catalysed rearrangement of bicyclo(4.3.0)-2β-hydroxy-2α-vinyl-1β-Methyl-8-oxo-Δ6,7-nonene |
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| Authors: | KY Geetha K Rajagopalan S Swaminathan |
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| Institution: | Department of Organic Chemistry, University of Madras, A.C. College Campus, Madras-600 025, India |
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| Abstract: | Synthesis and rearrangement of bicyclo(4.3.0) - 2β - hydroxy - 2α - vinyl - 1β - methyl - 8 - oxo - Δ6 - nonene was observed to yield a transannular reaction product tricycio - (6.3.0.01,8) - 2 - methyl - 8α - hydroxy - 4 - oxo - Δ2 - undecene 16. Spectral evidence supports the assigned structure. |
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