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三出口萃取工艺静态平衡研究
引用本文:张卫星 褚乃彬. 三出口萃取工艺静态平衡研究[J]. 应用化学, 1989, 6(5): 93-96
作者姓名:张卫星 褚乃彬
作者单位:中国科学院长春应用化学研究所(张卫星,褚乃彬),中国科学院长春应用化学研究所(李涵)
摘    要:三出口萃取工艺是在普通分馏萃取工艺中间级增开一个出口使之同时分离三个组份。采用这一工艺可大大简化多元体系分离流程,提高经济效益。本文根据恒定总萃取比体系的本出口萃取工艺中各组份的静态物料平衡,推导出四种三出口萃取工艺的极值公式。通过计算机静态模拟计算确定了Gd/Tb/Dy三出口萃取工艺参数,并通过试验验证了计算结果。

关 键 词:稀土  萃取分离  同时分离  极值公式
收稿时间:1988-10-24

A STUDY ON THE STATIC EQUILIBRIUM FOR THREE-EXIT EXTRACTION SEPARATION PROCESS
Zhang Weixing,Chu Naibin,Li Han Changchun Institute of Applied Chemistry,Academia Sinica. A STUDY ON THE STATIC EQUILIBRIUM FOR THREE-EXIT EXTRACTION SEPARATION PROCESS[J]. Chinese Journal of Applied Chemistry, 1989, 6(5): 93-96
Authors:Zhang Weixing  Chu Naibin  Li Han Changchun Institute of Applied Chemistry  Academia Sinica
Abstract:The three-exit extraction separation process(TESP) has been widely used in theseparation of rare earths. For the simultaneous separation of A/B/C, there are four kindsof TESP. Based on the static equilibrium of A, B and C. in extraction, formulae of theextreme values were derived for determing the separation parameters of the TESP. With computer simulation, parameters for the separation of Gd/Tb/Dy were determined.It is shown that Tb component has been richened from 4.5% to 53.5% with 98% recoveryin the experimental test.
Keywords:Rare earth  Extractive separation  Simultaneous separation  Formula of extreme value
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