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Study of retention of isomeric aromatic hydrocarbons on GTCB and cyclodextrins
Authors:E V Kalashnikova  K D Shcherbakova  E Smolková-Keulemansová  L Feltl
Institution:(1) Laboratory of Adsorption and Chromatography, Department of Chemistry, M.V. Lomonosov University of Moscow, 117234 Moscow, USSR;(2) Department of Analytical Chemistry, Charles University, Albertov 2030, 128 40 Prague 2, Czechoslovakia
Abstract:Summary A study has been made of the interaction between graphitized thermal carbon-black and cyclodextrins and a series of 28 derivatives of benzene (benzene, alkyl-, isoalkyl-, dialkyl-, trialkylbenzenes, vinyl-, and allyl-benzene). The specificretention volumes form the basis for a discussion of the mechanism of interaction and drawing conclusions for the practical separation of isomeric compounds.
Keywords:Gas-solid chromatography  Graphitized thermal carbon-black  Cyclodextrins  Retention of isomeric benzene derivatives
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