New coordination modes in potassium edta salts: K2[H2edta]·2H2O,K3[Hedta]·2H2O and K4[edta]·3.92H2O |
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Authors: | Monika K Krawczyk Tadeusz Lis |
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Abstract: | Three potassium edta (edta is ethylenediaminetetraacetic acid, H4Y) salts which have different degrees of ionization of the edta anion, namely dipotassium 2‐({2‐bis(carboxylatomethyl)azaniumyl]ethyl}(carboxylatomethyl)azaniumyl)acetate dihydrate, 2K+·C10H14N2O82?·2H2O, (I), tripotassium 2,2′‐({2‐bis(carboxylatomethyl)amino]ethyl}ammonio)diacetate dihydrate, 3K+·C10H13N2O83?·2H2O, (II), and tetrapotassium 2,2′,2′′,2′′′‐(ethane‐1,2‐diyldinitrilo)tetraacetate 3.92‐hydrate, 4K+·C10H12N2O84?·3.92H2O, (III), were obtained in crystalline form from water solutions after mixing edta with potassium hydroxide in different molar ratios. In (II), a new mode of coordination of the edta anion to the metal is observed. The HY3? anion contains one deprotonated N atom coordinated to K+ and the second N atom is involved in intramolecular bifurcated N—H...O and N—H...N hydrogen bonds. The overall conformation of the HY3? anions is very similar to that of the Y4? anions in (III), although a slightly different spatial arrangement of the –CH2COO? groups in relation to (III) is observed, whereas the H2Y2? anions in (I) adopt a distinctly different geometry. The preferred synclinal conformation of the –NCH2CH2N– moiety was found for all edta anions. In all three crystals, the anions and water molecules are arranged in three‐dimensional networks linked via O—H...O and C—H...O and N—H...O in (I) and (II)] hydrogen bonds. K...O interactions also contribute to the three‐dimensional polymeric architecture of the salts. |
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