The coordination polymer poly[(μ3‐3‐aminocarbonylpyrazine‐2‐carboxylato‐κ3N1:O2:O2′)silver(I)] |
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Authors: | Al‐shima'a A. Massoud,Vratislav Langer,Morsy A. M. Abu‐Youssef,Lars Ö hrströ m |
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Abstract: | The title compound, [Ag(C6H4N3O3)]n or [Ag(pyzca)]n (where pyzca is 3‐aminocarbonylpyrazine‐2‐carboxylate), (I), was obtained by silver‐catalysed partial hydrolysis of pyrazine‐2,3‐dicarbonitrile in aqueous solution. The compound has a distorted trigonal–planar coordination geometry around the AgI ion, with each ligand bridging three AgI ions to form a one‐dimensional strand of molecules parallel to the b axis. An extensive hydrogen‐bond pattern connects these strands to form a three‐dimensional network of mog topology. |
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