A synthetic route to heteronuclear clusters containing iridium and rhodium: X-ray crystal structures of [IrOs3(μ-H)2(μ-Cl)(CO)12] and [Ir2Rh2(μ-CO)(μ3-CO)2(CO)4(η-C5Me5)2] |
| |
Authors: | Louis J. Farrugia A.Guy Orpen F.Gordon A. Stone |
| |
Affiliation: | Department of Inorganic Chemistry, The University of Bristol, Bristol BS8 ITS England |
| |
Abstract: | The iridium and rhodium complexes [MCl(CO)2(NH2C6H4Me-4)] (M = Ir or Rh) react with [Os3(μ-H)2(CO)10] to give the tetranuclear clusters [MOs3(μ-H)2(μ-Cl)(CO)12]; the iridium compound being structurally identified by X-ray diffraction. Similarly, [IrCl(CO)2(NH2C6H4Me-4)] and [Rh2(μ-CO)2(η-C5Me5)2] afford the tetranuclear cluster [Ir2Rh2(μ-CO)(μ3-CO)2(CO)4(η-C5Me5)2], also characterised by single-crystal X-ray crystallog |
| |
Keywords: | |
本文献已被 ScienceDirect 等数据库收录! |