A synthetic route to heteronuclear clusters containing iridium and rhodium: X-ray crystal structures of [IrOs3(μ-H)2(μ-Cl)(CO)12] and [Ir2Rh2(μ-CO)(μ3-CO)2(CO)4(η-C5Me5)2] |
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| Authors: | Louis J Farrugia AGuy Orpen FGordon A Stone |
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| Institution: | Department of Inorganic Chemistry, The University of Bristol, Bristol BS8 ITS England |
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| Abstract: | The iridium and rhodium complexes MCl(CO)2(NH2C6H4Me-4)] (M = Ir or Rh) react with Os3(μ-H)2(CO)10] to give the tetranuclear clusters MOs3(μ-H)2(μ-Cl)(CO)12]; the iridium compound being structurally identified by X-ray diffraction. Similarly, IrCl(CO)2(NH2C6H4Me-4)] and Rh2(μ-CO)2(η-C5Me5)2] afford the tetranuclear cluster Ir2Rh2(μ-CO)(μ3-CO)2(CO)4(η-C5Me5)2], also characterised by single-crystal X-ray crystallog |
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