Hexahalogenotin(IV) complexes in aqueous mixed hydrogen halide solutions in the glassy state |
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| Authors: | M Katada H Kanno H Sano |
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| Institution: | Department of Chemistry Faculty of Science Tokyo Metropolitan University Fukasawa, Setagaya Tokyo 158, Japan |
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| Abstract: | The configurations of hexahalogenotin(IV) complex ions in glassy aqueous mixed hydrogen halide solutions were determined by Mössbauer and Raman spectroscopies. Trans-(SnF4Cl2)2-, (SnCl5Br)2- and (SnCl5Br)2- and trans-(SnF4Br2)2- ions are the main tin complex ions in the aqueous Sn(IV)-HF-HCl, Sn(IV)-HCl-HBr and Sn(IV)-HF-HBr solutions in the glassy state, respectively. |
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| Keywords: | Author to whom correspondence should be addressed at Department of Chemistry Meisei University Hodokubo Hino Tokyo 191 Japan |
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