Reactions of 2-thiazolin-2-ylthiophene with some metal ions |
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| Authors: | HA Tayim AS Salameh |
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| Institution: | Department of Chemistry, University of Petroleum & Minerals Dhahran, Saudi Arabia;Department of Chemistry, American University of Beirut Beirut, Lebanon |
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| Abstract: | The condensation of -aminobenzenthiol with 2-thiophenecarboxaldehyde yields 2-thiazolin-2-ylthiophene rather than the expected Schiff base. However, upon reaction with metal ions, the thiazoline rearranges to the expected thiolate Schiff base. Complexes of the Schiff base with Ni(II), Cu(II), Zn, Cd, Pb(II), Ag(I) and Pd(II) have been isolated and characterized. |
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| Keywords: | Author to whom correspondence should be addressed |
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