On the tri-n-octylammonium chlorocomplexes of Sn(II) in benzene solution |
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| Authors: | Claus Fischer Harald Wagner Vladimir V. Bagreev |
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| Affiliation: | Central Institute of Solid State Physics and Material Research, Academy of Sciences of the GDR, Dresden, GDR;V.I. Vernadsky Institute of Geochemistry and Analytical Chemistry, USSR Academy of Sciences, Moscow, U.S.S.R. |
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| Abstract: | Loading experiments in the extraction system TOAH+Cl?/benzene-SnCl2-HCl and measurements of the IR spectra and the specific conductivities κ of the extracts revealed the occurrence of two Sn(II)complexes: TOAH+SnCl3 (1:1-complex) and (TOAH…Cl…HTOA)+SnC13? (2:1-complex). The shift of the νNH frequencies of these complexes with N-deuteration, expressed by the ratio νHN/νND, amounts to 1.33 and 1.28 respectively. This agrees very well with corresponding values of complexes with analogous or similar composition. |
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| Keywords: | Author to whom correspondence should be addressed. |
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