Synthesis,molecular structure and electrochemistry of pentagonal bipyramidal nickel(II) complexes of quinquedentate macrocylic ligand incorporating a 2,2′:6′,2″-terpyridyl moiety |
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| Authors: | Edwin C. Constable Jack Lewis Michael C. Liptrot Paul R. Raithby Martin Schröder |
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| Affiliation: | University Chemical Laboratory Lensfield Road Cambridge CB2 1EW England |
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| Abstract: | The synthesis and single crystal X-ray structure of the pentagonal bipyramidal nickel(II) complex [Ni(L)(EtOH)2](BF4)2 involving the quinquedentate terpyridyl macrocyclic ligand L is reported; the electrochemical reduction of such complexes yields, in solution, d9 nickel(I) species. |
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