Ion exchange studies of U(VI), Th(IV), Pu(IV) and Eu(III) on a macroreticular resin in TBP-Shell Sol-T solutions |
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Authors: | P V Achuthan B L Jangida M Sundaresan |
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Institution: | (1) Fuel Reprocessing Division, Trombay, 400 085 Bombay, (India);(2) Analytical Chemistry Division, Bhabha Atomic Research Centre, Trombay, 400 085 Bombay, (India) |
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Abstract: | Ion exchange studies of uranium(VI), thorium(IV), plutonium(IV) and europium(III) ions on a macroreticular cation exchange resin, Amberlyst A-15, from solutions of 30% and 5% TBP—Shell Sol-T have been carried out. The metal ions were extracted into TBP Shell Sol-T phase from 8M NH4NO3 at different nitric acid concentrations. Ion exchange distribution ratios as a function of organic phase acidity of 30% and 5% TBP have been computed. Separation factors computed from the observed Kd values are plotted as a function of organic phase acidity. |
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