Kinetics of the thermal decomposition of N,N-(dinitro)alkylamines |
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| Authors: | B L Korsunskii G V Sitonina B S Fedorov F I Dubovitskii L T Eremenko |
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| Institution: | 1. N. N. Semenov Institute of Chemical Physics, Academy of Sciences of the USSR, USSR
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| Abstract: | | 1. |
The thermal decomposition of N,N-dinitroamines is homogeneous and unimolecular in the gas phase. The limiting step of the process is the rupture of the N-NO2 bond.
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The activation parameters of the process imply that the dinitroamine group is more reactive than the mononitroamine group in thermal decomposition. The energy of dissociation of the N-NO2 bond in dinitroamines is  42 kJ/mole less than in mononitroamines.
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Nitrogen dioxide and acetaldehyde do not influence the kinetics of thermal decomposition of dinitroamines due to their high reactivity.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 790–793, April, 1989. |
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