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A highly porous interpenetrated metal-organic framework from the use of a novel nanosized organic linker |
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| Authors: | Manos Manolis J Markoulides Marios S Malliakas Christos D Papaefstathiou Giannis S Chronakis Nikos Kanatzidis Mercouri G Trikalitis Pantelis N Tasiopoulos Anastasios J |
| Affiliation: | Department of Chemistry, University of Cyprus, 1678 Nicosia, Cyprus. |
| Abstract: | The initial use of a novel elongated tricarboxylic acid H(3)hmpib in metal-organic framework (MOF) chemistry resulted in a [Zn(4)O(hmpib)(2)] MOF (UCY-1) with pyrite topology. The compound displays a remarkably high internal surface area despite its double-interpenetrated structure as well as high CO(2) uptake and selective adsorption for it over CH(4). |
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