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Synthesis and properties of a novel squaraine dye modified by ferrocene
Authors:Yang Wei Huang  Nan Yan Fu
Affiliation:Fujian Provincial Key Laboratory of Photocatalysis-State Key Laboratory and Breeding Base Co-developed by Province and Ministry, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350002, China
Abstract:A novel squaraine dye (SQ) modified by ferrocene has been synthesized through (E)-1-dodecyl-2-ferrocenyl vinyl-1H-pyrrole and squaric acid. The molecular structure of SQ was characterized by 1H NMR, 13C NMR, MS and elemental analysis. SQ is high soluble in common solvents. The maximum absorptions of SQ in different solvents are in the range of 708−734 nm, exhibiting positive solvatochromism with increasing solvent polarity. The optical and electrical properties of SQ indicate that it is a promising electron donor material for bulk-heterojunction organic solar cell.
Keywords:Squaraine dye   Ferrocene   Bulk-heterojunction organic solar cell
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