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| Effect of noncovalent complexations on coordination interactions in a tricomponent system ofβ-cyclodextrin,copper chloride and hexamethylene tetramine | |
| 作者姓名： | Jing Yang Le Xin Song Zheng Dang Shu Zhen Pan Fang Yun Du |
| 作者单位： | a Department of Chemistry, University of Science and Technology of China, Hefei 230026, China;b State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China |
| 基金项目： | supported by NSFC(No21071139) |
| 摘 要： | This study reveals that the noncovalent complexation betweenβ-CD and Cu（HMTA）2+ makes a positive contribution to the coordination interaction between Cu2+ and HMTA in a tricomponent system.Besides,mono- and binuclear complexes:[β-CDCu]+ and[Cu·β-CDCu]+ were observed under the condition of ESI-MS. |
| 关 键 词： | Noncovalent complexation Coordination interaction β-Cyclodextrin Copper chloride |
| 收稿时间： | 2011-03-15 |
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