X-ray photoelectron spectroscopy and magnetism of Mn1−xAlxNi alloys |
| |
Authors: | V. Rednic M. Coldea M. Valente M. Neumann |
| |
Affiliation: | a Babes-Bolyai University, Faculty of Physics, 400084 Cluj-Napoca, Romania b University of Aveiro, Physics Department, 3810-193 Aveiro, Portugal c University of Osnabrück, Fachbereich Physik, 49069 Osnabrück, Germany |
| |
Abstract: | X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), magnetization and magnetic susceptibility of Mn1−xAlxNi alloys are reported. A change in the crystallographic structure takes place around x=0.4 from CuAuI to CsCl (B2) structure type. For x0.5 a mixed B2+L21 state exists which incorporates antiferromagnetic (B2) and ferromagnetic (L21) parts. A direct evidence for the existence of local moments on Mn sites in Mn1-xAlxNi alloys is given by the exchange splitting of XPS Mn 3s and Mn 2p3/2 core levels. The gradual filling of the Ni 3d band as the Al concentration increases can be explained by the hybridization of the Ni 3d band and Al 3sp states. |
| |
Keywords: | Transition metal Alloy Magnetic measurements XPS spectra Local moments |
本文献已被 ScienceDirect 等数据库收录! |
|