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Facile synthesis of diiodinated dihydronaphthalenes and naphthalenes via iodine mediated electrophilic cyclization
Authors:Yang Fan  Jin Tienan  Bao Ming  Yamamoto Yoshinori
Institution:Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8548, Japan.
Abstract:A facile, efficient, and general synthetic method for a wide range of 2,3-diiodinated 1,4-dihydrothiophenes and naphthalenes has been developed via the electrophilic iodocyclization of various aryl propargyl alcohols. The resulting product 2p can be used for the synthesis of a rubrene intermediate.
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