| Synthesis and Crystal Structure of a Puckered Rhombus Grid-like Coordination Polymer with Bridging Ligand Containing Sulfanyl Linker |
| |
| 作者姓名： | 韩磊 罗军华 洪茂椿 王瑞虎 林郑忠 曹荣 |
| |
| 作者单位： | State Key Laboratory of Structural Chemistry，Fujian Institute of the Research on the Structure of Matter，Chinese Academy of Sciences，State Key Laboratory of Structural Chemistry，Fujian Institute of the Research on the Structure of Matter，Chinese Academy of Sciences，State Key Laboratory of Structural Chemistry，Fujian Institute of the Research on the Structure of Matter，Chinese Academy of Sciences，State Key Laboratory of Structural Chemistry，Fujian Institute of the Research on the Structure of Matter，Chinese Academy of Sciences，State Key Laboratory of Structural Chemistry，Fujian Institute of the Research on the Structure of Matter，Chinese Academy of Sciences，State Key Laboratory of Structural Chemistry，Fujian Institute of the Research on the Structure of Matter，Chinese Academy of Sciences Fuzhou，Fujian 350002，China，Fuzhou，Fujian 350002，China，Fuzhou，Fujian 350002，China，Fuzhou，Fujian 350002，China，Fuzhou，Fujian 350002，China，Fuzhou，Fujian 350002，China |
| |
| 基金项目： | the National Natural Science Foundation of China (No. 20231020), the Natural Science Foundation of Fujian Province and Chinese Academy of Sciences. |
| |
| 摘 要： | Introduction The design and construction of metal-organic frameworks (MOFs), obtained by metal-directed self-assembly from labile metal centers and multidentate bridging ligands, is a rapidly developing area of su-pramolecular chemistry.1-3 Besides the aesthetic struc-tural and fascinating functional motifs, they are of in-terest both for understanding the mechanisms of the assembly process and for the host-guest chemistry asso-ciated with their large central cavities.4-13 It has been documen…
|
| 关 键 词： | 合成 聚合物 晶体结构 硫化物 |
Synthesis and Crystal Structure of a Puckered Rhombus Grid-like Coordination Polymer with Bridging Ligand Containing Sulfanyl Linker |
| |
| HAN,Lei LUO,Jun-Hua HONG,Mao-Chun WANG,Rui-Hu LIN,Zheng-Zhong CAO,Rong State Key Laboratory of Structural Chemistry,Fujian Institute of the Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou,Fujian ,China.Synthesis and Crystal Structure of a Puckered Rhombus Grid-like Coordination Polymer with Bridging Ligand Containing Sulfanyl Linker[J].Chinese Journal of Chemistry,2004,22(1):51-54. |
| |
| Authors: | HAN Lei LUO Jun-Hua HONG Mao-Chun WANG Rui-Hu LIN Zheng-Zhong CAO Rong State Key Laboratory of Structural Chemistry Fujian Institute of the Research on the Structure of Matter Chinese Academy of Sciences Fuzhou Fujian China |
| |
| Institution: | HAN,Lei LUO,Jun-Hua HONG,Mao-Chun WANG,Rui-Hu LIN,Zheng-Zhong CAO,Rong State Key Laboratory of Structural Chemistry,Fujian Institute of the Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou,Fujian 350002,China |
| |
| Abstract: | A new coordination polymer with sulfide moieties, Co(ptmb)2] · 0.25H2O (ptmb=4–(4‐pyridylthiomethyl)‐benzoate), was synthesized by self‐assembly of Co(NO3)2 · 6H2O with Hptmb under solvothermal conditions. X‐ray single crystal diffraction study shows that it is a 2D layer structure consisting of puckered rhombus grid with dimensions 1.175 nm ×1.110 nm. |
| |
| Keywords: | crystal structure coordination polymer solvothermal synthesis sulfide moiety |
| 本文献已被 CNKI 等数据库收录！ |
