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Alkane C-H activation and catalysis by an O-donor ligated iridium complex
Authors:Wong-Foy Antek G  Bhalla Gaurav  Liu Xiang Yang  Periana Roy A
Affiliation:Loker Hydrocarbon Research Institute, Department of Chemistry, University of Southern California, Los Angeles, CA 90089, USA.
Abstract:The first examples of well-defined, O-donor ligated, late-metal complexes that are competent for alkane C-H activation are reported. These complexes exhibit thermal and protic stability and are efficient catalysts for H/D exchange reactions with alkanes.
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