Gold(I)-catalyzed hydroarylation of allenes with indoles |
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| Authors: | Kristina L Toups Gordon T Liu Ross A Widenhoefer |
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| Institution: | Department of Chemistry, French Family Science Center, Duke University, 124 Science Drive, Durham, NC 27708-0346, United States;Organisch-Chemisches Institut, Universität Heidelberg, Heidelberg, Germany |
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| Abstract: | Reaction of a monosubstituted, 1,3-disubstituted, or tetrasubstituted allene with various indoles catalyzed by a 1:1 mixture of a gold(I) N-heterocyclic carbene complex and AgOTf at room temperature leads to hydroarylation with formation of 3-allyl-indoles in modest to good yield. |
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