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Kerr studies of several tellurite glasses
Authors:JR Duclère  AA Lipovskii  AP Mirgorodsky  Ph Thomas  DK Tagantsev  VV Zhurikhina
Institution:1. Sciences des Procédés, Céramiques et de Traitements de Surfaces, UMR 6638 CNRS, Faculté des Sciences et Techniques, 123 av. A. Thomas, 87060 Limoges, France;2. St. Petersburg State Polytechnical University, Polytechnicheskaja 29, St. Petersburg 195251, Russia;3. Research and Technological Institute of Optical Materials Science, Babushkina 36-1, St. Petersburg 193171, Russia
Abstract:Estimates of Kerr electrooptical sensitivity of several tellurite glasses are presented. The highest value of Kerr coefficient B  190 × 10?16 m V?2 is registered for 0.6TeO2–0.3TlO0.5–0.1ZnO glass. This evidences the prospects of thallium–tellurite glass system for electrooptical applications. A gradual decrease of B from 41 × 10?16 to 26 × 10?16 m V?2 in (1 ? x) TeO2  xNbO2.5 system is revealed for x increasing from 0.1 to 0.15. No crystalline phase was found in that system, thus allowing attributing its Kerr sensitivity to the intrinsic properties of the glass matrix. The Kerr coefficient variation from 66 to 81 × 10?16 m V?2 was observed for 0.85TeO2–0.15WO3 glasses co-doped with small amounts of silver and cerium. The analysis of optical absorption spectra of several silver-containing tellurium–tungsten oxide glasses makes it possible to think that introducing cerium provokes formation of new mid-range orderings.
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