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CsPbCl3 nanocrystals dispersed in the Rb0,8Cs0,2Cl matrix studied by far-infrared spectroscopy
Authors:A Voloshynovskii  P Savchyn  I Karbovnyk  S Myagkota  M Cestelli Guidi  M Piccinini  AI Popov
Institution:1. Ivan Franko National University of Lviv, Department of Physics, 8 Kyrylo and Mefodii street, 79005, Lviv, Ukraine;2. Ivan Franko National University of Lviv, Department of Electronics, 107 Tarnavskogo street, 79017, Lviv, Ukraine;3. Lviv State Agrarian University, Dubljany, Lviv, Ukraine;4. INFN–Laboratori Nazionali di Frascati, Via E. Fermi 40, 00044 Frascati, Italy;5. Institute for Solid State Physics, University of Latvia, Kengaraga 8, LV-1063 Riga, Latvia;6. Institute Laue Langevin, 6 rue Jule Horovitz, 38042, Grenoble, France;1. Key Laboratory of Optoelectronic Technology & Systems (Ministry of Education), Chongqing University, Chongqing 400044, China;2. State Key Laboratory of High Field Laser Physics, Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800, China;3. Institute of Polymer Optoelectronic Materials and Devices State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, Guangzhou 510640, PR China;4. Department of Materials Science & Engineering, Wuhan University of Technology, China;5. School of Physical Science and Technology, Shanghai Tech University, Shanghai 201210, China;1. Department of Physics, M.L. Sukhadia University, Udaipur 313301, Rajasthan, India;2. Department of Pure and Applied Physics, University of Kota, Kota 324010, India;1. Reception and Quality Control Department Assurance Service, Material Resources Directorate, Ministry of Defence of the Republic of Croatia, Sarajevska 7, 10000 Zagreb, Croatia;2. Division of Physical Chemistry, Ru?er Bo?kovi? Institute, Bijeni?ka cesta 54, 10000 Zagreb, Croatia;3. Department of Hygiene and Technology of Foodstuffs, Faculty of Veterinary Medicine, University of Zagreb, Heinzelova 55, 10000 Zagreb, Croatia;1. Key Laboratory of Artificial Micro- and Nano-structures of Ministry of Education, Department of Electronic Science and Technology, School of Physics and Technology, Wuhan University, Wuhan, Hubei 430072, People''s Republic of China;2. Laboratory of Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, People''s Republic of China;3. School of Electronic and Electrical Engineering, Wuhan Textile University, Wuhan, Hubei 430073, People''s Republic of China
Abstract:The comparative far-infrared spectroscopy studies of Rb0.8Cs0.2Cl and Rb0.8Cs0.2Cl containing CsPbCl3 nanocrystals between 170 and 320 K are reported. The effect of cesium lead chloride nanocrystals on the phonon modes of the host matrix, particularly manifested in different temperature behavior of LO–TO splitting and the temperature dependence of high frequency dielectric constant, are demonstrated.
Keywords:
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