Ir(III) complexes of diamine ligands for asymmetric ketone hydrogenation |
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Authors: | José ED Martins Martin Wills |
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Institution: | Department of Chemistry, The University of Warwick, Coventry CV4 7AL, UK |
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Abstract: | The use of a combination of IrCl3 with a series of ligands derived from the C2-symmetric diamine diphenylethanediamine (DPEN) forms a catalyst capable of the asymmetric hydrogenation of ketones in up to 85% ee. |
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