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A novel solvolytic rearrangement of 2,2-dimethyl-5-(1-Bromomethylethylidene)-1, 3-dioxane-4,6-dione |
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| Authors: | Norman R Hunter Nancy A Green David M McKinnon |
| Institution: | Department of Chemistry, University of Manitoba, Winnipeg, Manitoba, Canada R3T 2N2 |
| Abstract: | Treatment of the title compound under basic aqueous conditions leads to 2,2-dimethyl-5-(2-ketopropyl)-1,3-dioxane-4,6-dione; the structure and mechanism of formation of this compound is described. |
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