Thermal studies on the decomposition of aquopentamminecobalt(III) hexathiocyanatochromate(III) |
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| Authors: | JE House Camille A Jepsen |
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| Institution: | Department of Chemistry, Illinois State University, Normal, Ill. 61761 U.S.A. |
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| Abstract: | The decomposition of Co(NH3)5H2O] Cr(NCS)6] has been studied using DSC and TG. The first step involves the loss of H2O and NH3 in a first-order process to produce (NH3)5Co(SCN)3Cr(NCS)3]. A second step involves the loss of HSCN. Activation energies are presented and the mechanisms of the reactions are discussed in comparison to analogous cyanide complexes. |
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