Optical resolution of tricarbonyl(1-carboxycyclohexa-1,3-diene) iron and the absolute configuration of the products |
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Authors: | Arthur J. Birch B.M.Ratnayake Bandara |
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Affiliation: | Research School of Chemistry, Australian National University, P.O. Box 4, Canberra, A.C.T. 2600, Australia |
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Abstract: | Resolution of the acid () (shown as the (+)-isomer) into its optically pure (+) and (?) isomers and reduction of the CO2H yields the 2-Me derivative () (shown as the (?)-isomer). The absolute configuration of () is defined by conversion of the salt () of known configuration into () and (). This is the first resolution leading to preparation of pure complexes of known absolute configuration. |
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