Photocyclization of benzofurancarboxanilides. Photorearrangement of the benzodihydrofuran system to 3-o-hydroxyphenylquinolones |
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Authors: | Yuichi Kanaoka Kunio San-nohe |
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Institution: | Faculty of Pharmaceutical Sciences, Hokkaido University, Sapporo 060 Japan |
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Abstract: | -Dihydrobenzofuro2,3-c]quinolone () and -dihydrobenzofuro-3,2-c]quinolone () undergo photorearrangement, characteristic to the benzodihydrofuran system, leading to 3--hydroxyphenylquinolone (). A plausible mechanism involving a cyclopropyl dienone () was discussed. |
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