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Photocyclization of benzofurancarboxanilides. Photorearrangement of the benzodihydrofuran system to 3-o-hydroxyphenylquinolones
Authors:Yuichi Kanaoka  Kunio San-nohe
Institution:Faculty of Pharmaceutical Sciences, Hokkaido University, Sapporo 060 Japan
Abstract:cis-Dihydrobenzofuro2,3-c]quinolone (4a) and cis-dihydrobenzofuro-3,2-c]quinolone (5) undergo photorearrangement, characteristic to the benzodihydrofuran system, leading to 3-o-hydroxyphenylquinolone (6). A plausible mechanism involving a cyclopropyl dienone (12) was discussed.
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