Investigation of phase equilibria in the systems K2SO4Sc2(SO4)3, Rb2SO4Sc2(SO4)3 and Cs2SO4Sc2(SO4)3 |
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Authors: | F.M. Korytnaya A.N. Pokrovsky P.A. Degtyarev |
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Affiliation: | Chair of General Chemistry, Department of Chemistry, Moscow State University, Moscow 117234 U.S.S.R. |
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Abstract: | Phase diagrams of the systems K2SO4Sc2(SO4)3, Rb2SO 4Sc2(SO4)3 and Cs2SO4 Sc2(SO4)3 have been investigated by X-ray diffraction phase analysis and differential thermal analysis techniques. A salient feature of all the systems is the formation of M3Sc(SO4)3, which melt incongruently, and MSc(SO4)2, which on heating decompose in the solid state. |
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