Tris-Nethyl, m-tolyl)dithiocarbamato complexes of arsenic(III), antimony(III) and bismuth(III) |
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Authors: | Shyam Kumar Narendra Kumar Kaushik |
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Affiliation: | Department of Chemistry, University of Delhi, Delhi-110007 India |
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Abstract: | Tris-N(ethyl, m-tolyl) dithiocarbamato complexes of arsenic(III), antimony(III) and bismuth(III) abbreviated as As(S2CNRR′)3 Sb(S2CNRR′)3 and Bi(S2CNRR′)3, respectively, where R C2H5 and R′ m-C6H4CH3, have been synthesized. These complexes have been characterized on the basis of elemental analyses, molecular weight determinations, conductance measurements and infrared spectral studies. Thermal studies of these complexes have been carried out in nitrogen and air to determine their modes of decomposition. Kinetic parameters, such as apparent activation energy and order of reaction, have been determined by the graphical method of Coats and Redfern [1]. |
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