Carbon-13 chemical shifts of inverted carbon atoms |
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| Authors: | Zdenko Majerski Katica Mlinari?-Majerski Zlatko Mei? |
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| Institution: | Rudjer Bo?kovi? Institute, 41001 Zagreb, Croatia, Yugoslavia |
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| Abstract: | The inverted carbons in 2,4-methano-2,4-dehydroadamantane are shielded by 14.3 ppm relative to the corresponding carbons in 2,4-methanoadamantane. This was explained by the balance of the inverted carbon hybridization deshielding, the shielding effect of the cyclopropane rings formed, and the change in the influence of the neighbouring atoms. |
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