Studies in sesquiterpenes—LVI: Isolongifolene (part 7): mechanism of rearrangement of longifolene to isolongifolene—II |
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| Authors: | J.S. Yadav R. Soman R.R. Sobti U.R. Nayak Sukh Dev |
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| Affiliation: | National Chemical Laboratory, Poona, India |
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| Abstract: | The question of possible neutral intermediates which may lie on the reaction pathway in going from longifolene to isolongifolene has been investigated using BF3·Et2O-AcOD and D3PO4-dioxane, as reagents. It has been found that longicyclene is not an obligatory intermediate. The mode of cleavage of cyclopropane ring in longicyclene has been investigated. |
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| Keywords: | Present address:Malti-Chem Research Centre Nandesari Vadodara India |
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