Tricarbonylcyclohexadienyliron complexes : synthetic equivalents of aryl cations; a facile synthesis of 2-aryl-cyclopentenones and its application towards prostaglandin analogues |
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| Authors: | Arthur J Birch Peter Dahler Acharan S Narula GRichard Stephenson |
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| Institution: | Research School of Chemistry, Australian National University, P.O. Box 4, Canberra, A.C.T. 2600, Australia |
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| Abstract: | Tricarbonylcyclohexadienyliron cations of type 1 are converted, by alkylation with 1,2-bis(trimethylsiloxy)-1-cyclopentene, dehydration and subsequent dehydrogenation, into specifically substituted 2-aryl-2-cyclopentenones. |
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