Reaction of cholest-4-ene-3,6-dione with perbenzoic acid : Formation of novel oxetalactones |
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| Authors: | MS Ahmad Israr A Khan NK Pillai |
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| Institution: | Department of Chemistry, Aligarh Muslim University, Aligarh, India |
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| Abstract: | Oxidation of 1 with perbenzoic acid (p-toluene-sulphonic acid monohydrate as catalyst) provided novel oxetalactones 4 and 5 along with compounds 2 and 3. Treatment of 2 with perbenzoic acid yielded 4. A probable pathway for the formation of 4 from 1 involving the intermediacy of 2 has been suggested. |
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