Reduction of Z-2-chlorostilbene with lithium aluminum hydride: evidence for an electron transfer radical mechanism |
| |
Authors: | P.R. Singh Alok Nigam J.M. Khurana |
| |
Affiliation: | Department of Chemistry, Indian Institute of Technology, Kanpur-208016, India |
| |
Abstract: | -2-Chlorostilbene undergoes uncatalyzed LiAlH4 reduction giving phenanthrene and -stilbene. An electron transfer radical mechanism is proposed. LiAlH4 induced isomerization of -stilbene produces -stilbene. |
| |
Keywords: | |
本文献已被 ScienceDirect 等数据库收录! |