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Dimethylaluminum halide induced reactions of formaldehyde with alkynes. Synthesis of α-allenic alcohols and Z-3-chloroallylic alcohols |
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| Authors: | David J Rodini Barry B Snider |
| Institution: | Department of Chemistry Princeton University Princeton, New Jersey 08544 USA |
| Abstract: | The CH2O·Me2AlCl complex reacts with terminal alkynes to give α-allenic alcohols via a formal ene reaction and Z-3-chloroallylic alcohols via a stereospecifically syn Friedel-Crafts addition. |
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