A novel method for the terpene synthesis by the ring-opening reaction of β-methyl-β-propiolactone |
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| Authors: | Tamotsu Fujisawa Toshio Sato Tatsuo Kawara Atsunari Noda Toshiyuki Obinata |
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| Institution: | Chemistry Department of Resources, Mie University, Tsu, Mie 514, Japan |
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| Abstract: | A new route for the terpene synthesis is investigated, which undergoes via terpene carboxylic acids as key intermediates obtained by the regiospecific ring opening of β-methyl-β-propiolactone with a cuprate or with a Grignard reagent in the presence of a copper catalyst. |
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