Oxidative
degradation of EVA copolymers in the presence of catalysts |
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Authors: | A Marcilla A Gómez-Siurana S Menargues |
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Institution: | (1) Departamento Ingeniería Química, Universidad de Alicante, Alicante, Spain, 03080, Apdo. 99 |
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Abstract: | A study of the catalytic degradation of EVA
copolymers under air atmosphere has been carried out using thermogravimety
(TG). Three commercial EVA copolymers and five zeolites and related materials
catalysts have been selected. The degradation process in air atmosphere involves
four main decomposition steps (as observed in TG), being more complex than
the corresponding process in inert atmosphere. The presence of MCM-41, HY
and H-β does not seem to noticeably affect to the overall degradation
temperature, despite the temperature of maximum reaction rate for the second
decomposition step being slightly displaced towards lower temperatures. Contrarily,
the presence of HZSM-5 and HUSY zeolites seems to displace the main stage
of the oxidative degradation process towards higher temperatures. Moreover,
the relative importance of the second and third decomposition step is different
depending on the amount and the nature of the zeolite mixed with the EVA sample.
The results obtained show that the presence of the catalyst also enhances
the formation of the carbonous residue. |
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Keywords: | degradation EVA copolymers MCM-41 oxidative TG zeolites |
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