Dipolar double-quantum filtered rotational-echo double resonance |
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| Authors: | Matsuoka Shigeru Schaefer Jacob |
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| Affiliation: | Department of Chemistry, Washington University, St. Louis, Missouri 63130, USA. |
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| Abstract: | The homonuclear dipolar coupling of a directly bonded (13)C-(13)C pair has been used to create a dipolar double-quantum filter (D-DQF) to remove the natural-abundance (13)C background in (13)C[(2)H] rotational-echo double-resonance (REDOR) experiments. The most efficient version of this experiment has the D-DQF excitation and reconversion preceding the REDOR evolution period. Calculated and observed (13)C[(2)H]D-DQF-REDOR dephasings were in agreement for a test sample of mixed recrystallized labeled alanines. |
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