Synthesis of 2-arylhydrazones of aliphatic fluorine-containing 1,2,3-tricarbonyl compounds and their reactions with dinucleophiles |
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Authors: | O. G. Kuzueva Ya. V. Burgart V. I. Saloutin |
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Affiliation: | (1) Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, 20 ul. S. Kovalevskoi, 620219 Ekaterinburg, Russian Federation |
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Abstract: | New fluorinated 2-arylhydrazones of 1,2,3-tricarbonyl compounds were obtained by coupling fluorine-containing 3-oxo esters, 1,3-diketones, and their copper chelates with aryldiazonium chlorides. Reactions of these arylhydrazones with hydrazine hydrate, phenylhydrazine, thiosemicarbazide, and hydroxylamine gave the corresponding pyrazole and isoxazole derivatives. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 695–700, April, 1998. |
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Keywords: | azo-coupling aliphatic fluorine-containing 1,3-dicarbonyl compounds arylhydrazones pyrazole isoxazole |
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