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氧化物纳米材料Y2O3:(Yb3+,Er3+)上转换发光性质的研究
引用本文:刘晃清,王玲玲,李宏健. 氧化物纳米材料Y2O3:(Yb3+,Er3+)上转换发光性质的研究[J]. 光谱学与光谱分析, 2006, 26(8): 1396-1399
作者姓名:刘晃清  王玲玲  李宏健
作者单位:湖南大学应用物理系,湖南,长沙,410082;湖南大学应用物理系,湖南,长沙,410082;湖南大学应用物理系,湖南,长沙,410082
摘    要:以Y2O3,Yb2O3,Er2O3为原料,利用燃烧法分别制备了Y2O3:Er3 和Y2O3:(Yb3 ,Er3 )两种纳米材料和相应的体材料Y2O3:(Yb3 ,Er3 ).用发射波长为978 nm的半导体激光器和日立F-4500荧光分析仪测量了它们的上转换发光,得到纳米材料Y2O3:Er3 的上转换发光主要为绿色上转换发射而纳米材料Y2O3:(Yb3 ,Er3 )主要为红色上转换发射,而后者与激活离子掺杂浓度相同的体材料Y2O3:(Yb3 ,Er3 )的上转换发射相比较,体材料以绿色上转换发射为主、红色上转换发射很弱.

关 键 词:氧化物  纳米材料  Y2O3:(Yb3+  Er3+)  上转换  发光
文章编号:1000-0593(2006)08-1396-04
收稿时间:2005-04-30
修稿时间:2005-10-20

Upconversion of Oxide Y2O3 Doped with (Yb3+, Er3+) Ions with 978 nm Excitation
LIU Huang-qing,WANG Ling-ling,LI Hong-jian. Upconversion of Oxide Y2O3 Doped with (Yb3+, Er3+) Ions with 978 nm Excitation[J]. Spectroscopy and Spectral Analysis, 2006, 26(8): 1396-1399
Authors:LIU Huang-qing  WANG Ling-ling  LI Hong-jian
Affiliation:Department of Applied Physics, Hunan University, Changsha 410082, China
Abstract:Two nanomaterials Y_2O_3: Er~(3 ) and Y_2O_3:(Yb~(3 ),Er~(3 )) were prepared by combustion on the basis of reagents Y_2O_3,Yb_2O_3 and Er_2O_3.The corresponding host Y_2O_3:(Yb~(3 ),Er~(3 )) was obtained by increasing calcination temperature.Upconversion emission was obtained under 978 nm LD excitation.Comparing nanopowder oxide Y_2O_3:Er~(3 ) with nanometer materials Y_2O_3:(Yb~(3 ),Er~(3 )) with respect to upconversion spectra,the upconversion emission of the former mainly was green upconversion and that of the latter mainly red light.However,the upconversion emission of nanopowder Y_2O_3:(Yb~(3 ),Er~(3 )) was different from that of its corresponding host,with main red upconversion emission for the former but main green upconversion emission on the latter.
Keywords:Oxide  Nanomaterials  Y_2O_3:(Yb~(3 )  Er~(3 ))  Upconversion  Luminescence
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