First example of high loaded polymer-stabilized nanoclusters immobilized on hydrotalcite: effects in alkyne hydrogenation |
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| Authors: | Roelofs Jules C A A Berben Peter H |
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| Affiliation: | Engelhard De Meern b.v. Strijkviertel 67, 3454 ZG De Meern, The Netherlands. jules.roelofs@Engelhard.com |
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| Abstract: | Poly(N-vinyl-2-pyrrolidone)-stabilized Pd-nanoclusters, for the first time exclusively supported on the hydrotalcite lateral surface, showed a remarkable catalytic performance in the selective hydrogenation of 3-hexyn-1-ol, which can be ascribed to both the influence of the protecting polymer PVP as well as the nature of the support. |
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