| 分子基磁体[NCBzPy][Ni(dmit)2]的合成、表征和磁学性质 |
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| 引用本文： | 陈友存,刘光祥.分子基磁体[NCBzPy][Ni(dmit)2]的合成、表征和磁学性质[J].合成化学,2004,12(5):418-420. |
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| 作者姓名： | 陈友存 刘光祥 |
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| 作者单位： | 安庆师范学院化学系,安徽,安庆,246003;安庆师范学院化学系,安徽,安庆,246003 |
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| 基金项目： | theNationalNaturalScienceFoundationofChina( 2 0 3 71 0 0 2 )，SupportedbytheNaturalScienceFoundationofAnhuiProminceEducationCommission( 2 0 0 3kj2 5 1 ,2 0 0 3kj2 5 3 ) |
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| 摘 要： | 合成了一种新的取代苄基吡啶盐NcBzpy]cl(1)，1和NiCl2，dmit^2-反应生成分子基磁体NCBzPy]Ni(dmit)2](2)，其结构用元素分析、IR和UV进行了表征。并测定了2在2K～300K的变温磁化率，结果显示。相邻Ni^3 之间存在铁磁偶合作用。
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| 关 键 词： | 分子基磁体 dmit 合成 磁性 |
Synthesis,Characterization and Magnetic Properties of Molecule-based Magnet [NCBzPy][Ni(dmit)2] |
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| Abstract.Synthesis,Characterization and Magnetic Properties of Molecule-based Magnet [NCBzPy][Ni(dmit)2][J].Chinese Journal of Synthetic Chemistry,2004,12(5):418-420. |
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| Authors: | Abstract |
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| Abstract: | A new substituted benzylpridiniums NCBzPy]Cl was synthesized, futher, a molecule-based magnet NCBzPy]Ni(dmit)2] was synthesized and characterized by elemental analysis, IR and UV spectra. Its magnetic susceptibility data has been measured in the temperature range of 2K～300 K, and the results indicated that there exist ferromagnetic coupling interactions between neighbor Ni(Ⅲ) ions. |
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| Keywords: | molecule-based magnet dmit synthesis magnetic property |
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