| 金属有机框架材料在毛细管电色谱中的应用 |
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| 引用本文： | 潘聪洁,陈兴国. 金属有机框架材料在毛细管电色谱中的应用[J]. 分析测试技术与仪器, 2020, 26(4): 228-238. DOI: 10.16495/j.1006-3757.2020.04.002 |
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| 作者姓名： | 潘聪洁 陈兴国 |
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| 作者单位： | 兰州大学化学化工学院, 甘肃 兰州 730000 |
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| 基金项目： | 国家自然科学基金21675068 |
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| 摘 要： | 金属有机框架材料(MOFs)是一类由金属离子或金属簇与有机官能团通过配位键形成的新型有机-无机杂化晶态多孔材料, 具有比表面积大、热稳定性和化学稳定性高、结构及功能多样等特点, 是毛细管电色谱(CEC)领域研究较多且具有优异应用前景的一类新型纳米材料固定相.综述了近年来MOFs在CEC中的研究进展, 主要包括新型制柱技术的发展及其在分离领域的应用, 并对该领域今后的发展方向进行了展望.
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| 关 键 词： | 金属有机框架材料 毛细管电色谱 固定相 分离 |
| 收稿时间： | 2020-11-18 |
Application of Metal Organic Frameworks in Capillary Electrochromatography |
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| Affiliation: | College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China |
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| Abstract: | Metal organic frameworks (MOFs) are an emerging class of organic-inorganic hybrid crystalline porous materials formed by the coordination bonds of metal ions or metal clusters with organic ligands.Owing to the advantages of large specific surface area, good thermal stability and chemical stability, diverse structures and functionality, the application of MOFs as the stationary phase of capillary electrochromatography (CEC) has attracted much attention in recent years.In this review, the recent advances in the application of MOFs in CEC, including the development of novel coating techniques and their application in separation field are summarized.The prospects of MOFs in CEC are also presented. |
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