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Effect of Fe impurity on the optical loss of Nd-doped phosphate laser glass
作者姓名:徐永春  李顺光  胡丽丽  陈伟
作者单位:Shanghai Institute of Optics and Fine Mechanics Chinese Academy of Sciences,Shanghai 201800,Shanghai Institute of Optics and Fine Mechanics,Chinese Academy of Sciences,Shanghai 201800,Shanghai Institute of Optics and Fine Mechanics,Chinese Academy of Sciences,Shanghai 201800,Shanghai Institute of Optics and Fine Mechanics,Chinese Academy of Sciences,Shanghai 201800
摘    要:The optical loss coefficient at 1053-nm wavelength, influenced by Fe ions in N31-type Nd-doped phosphate laser glass, was determined precisely and analyzed in detail. It is found that the optical loss coefficient per unit of Fe concentration (cm-1/ppmw) increases with Fe concentration in the range of 0-300 ppmw, but it approaches a constant as the Fe concentration is larger than 300 ppmw. Such a concentration effect is due to a shift in the redox equilibrium between Fe3+ and Fe2+ ions in the glass. The effect of oxygen pressure, temperature, and variable valence states of other metal ions in glass samples on the optical loss is also discussed.

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