| 新颖的二维超分子化合物[CoⅢ(aea)(2,2'-bipy)]Cl·H2O的水热合成及结构表征 |
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| 引用本文： | 谢凤桐,段莉梅,徐吉庆,刘亚冰,张潇,卢静.新颖的二维超分子化合物[CoⅢ(aea)(2,2''''-bipy)]Cl·H2O的水热合成及结构表征[J].无机化学学报,2005,21(1). |
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| 作者姓名： | 谢凤桐 段莉梅 徐吉庆 刘亚冰 张潇 卢静 |
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| 作者单位： | 1. 吉林大学无机合成与制备化学国家重点实验室,长春,130023;内蒙古通辽市产品质量计量检验所,通辽,028000
2. 吉林大学无机合成与制备化学国家重点实验室,长春,130023 |
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| 基金项目： | 国家自然科学基金资助项目(No.2033307020271021)，国家重点基础研究发展规化项目(No.2001CB108906) |
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| 摘 要： | 0IntroductionInrecentyearsgreatattentionhasbeenpaidtosupramolecularchemistryandawidevarietyofnet鄄workshavealreadybeenconstructedbasedupontheprincipleofcrystalengineering1~3].Usually,variousmultifunctionalorganicligands,bothrigidandflexiblemulticarboxyli…
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| 关 键 词： | 超分子网络 原位反应 Co(Ⅲ)配合物 四齿配体 |
Hydrothermal Synthesis and Structural Characterization of a Novel 2-D Supramolecular Compound [CoⅢ(aea)(2,2'-bipy)]Cl·H2O |
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| XIE Feng-Tong, DUAN Li-Mei XU Ji-Qing, LIU Ya-Bing ZHANG Xiao LU Jing.Hydrothermal Synthesis and Structural Characterization of a Novel 2-D Supramolecular Compound [CoⅢ(aea)(2,2''''-bipy)]Cl·H2O[J].Chinese Journal of Inorganic Chemistry,2005,21(1). |
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| Authors: | XIE Feng-Tong DUAN Li-Mei XU Ji-Qing LIU Ya-Bing ZHANG Xiao LU Jing |
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| Institution: | XIE Feng-Tong1,2 DUAN Li-Mei1 XU Ji-Qing*,1 LIU Ya-Bing1 ZHANG Xiao1 LU Jing1 |
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| Abstract: | A new compound CoⅢ(aea)(2,2'-bipy)]Cl·H2O (aea=N-(2-aminoethyl)aspartate, 2,2'-bipy=2,2'-bipyridine) was hydrothermally synthesized and structurally characterized, which contains a new quadridentate ligand (aea) came from malic acid and ethylenediamine via in-situ reaction. The asymmetric molecules are interconnectgroup in malate by ethylenediamino group, which presents a type of new in-situ ligand reaction. CCDC: 222018. |
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| Keywords: | supramolecular network in-situ reaction cobalt(Ⅲ) complex quadridentate |
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