Heterobimetallic dianionic guanidinate complexes of lanthanide and lithium: highly efficient precatalysts for catalytic addition of amines to carbodiimides to synthesize guanidines |
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| Authors: | Xingmin ZhangChuanyong Wang Cunwei QianFubin Han Fan XuQi Shen |
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| Affiliation: | a College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, People’s Republic of China
b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, People’s Republic of China |
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| Abstract: | A series of heterobimetallic dianionic guanidinate complexes of lanthanide and lithium, [Li(THF)(DME)]3Ln[μ-η2η1(iPrN)2C(NC6H4p-R)]3 [R=Cl, Ln=Nd (I), Y (II), La (III); R=H, Ln=Nd (IV)] were synthesized and fully characterized. These complexes were found to be highly efficient precatalysts for the addition of various primary and secondary amines, and aromatic and aliphatic diamines to carbodiimides to give the corresponding monoguanidine and biguanidine derivatives under mild condition (at 25-60 °C), which provides an efficient way for the synthesis of biguanidines compounds. The activity depends on the central metals and ligands: La>Nd>Y for the metals and [(iPrN)2C(NC6H4p-Cl)]2−>[(iPrN)2C(NC6H5)]2− for the ligands were observed. |
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| Keywords: | Heterobimetallic complexes Catalysis Addition Guanidines |
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