A solid-state redox buffer as interface of solid-contact ISEs |
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Authors: | Fritz Scholz Heike Kahlert Ulrich Hasse Anja Albrecht Alain C Tagne Kuate Klaus Jurkschat |
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Institution: | 1. Universität Greifswald, Institut für Biochemie, Felix-Hausdorff-Straße 4, D-17489 Greifswald, Germany;2. Technische Universität Dortmund, Lehrstuhl für Anorganische Chemie II, D-44221 Dortmund, Germany |
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Abstract: | Graphite with a surface-confined redox buffer system was used as solid contact in solid-contact ion-selective electrodes (SC-ISE). Potentiostatically preconditioning of the redox buffer ensures that the ratio of oxidized and reduced groups is unity, i.e., a maximum buffer capacity. These SC-ISEs exhibited a very high reproducibility and stability of potentials. Graphite modification was achieved by generating carboxylic surface groups via oxidation with nitrosulfuric acid and subsequent modification of the acidic groups with n-(2,5-dimethoxyphenyl)ethyl-1-amine (DMPEA). Composite electrodes of modified graphite and polymethylmetharcrylate (PMMA) as binder were used as solid-contact of polymer membrane K+-and F?-sensitive SC-ISEs. The solid-state redox buffer decreased potential variation from several hundred mV to just a few mV. |
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